دورية أكاديمية

Alkaline Hydrolysis of Waste Acrylic Fibers Using the Micro-Water Method and Its Application in Drilling Fluid Gel Systems

التفاصيل البيبلوغرافية
العنوان: Alkaline Hydrolysis of Waste Acrylic Fibers Using the Micro-Water Method and Its Application in Drilling Fluid Gel Systems
المؤلفون: Wenjun Long, Zhongjin Wei, Fengshan Zhou, Shaohua Li, Kang Yin, Yu Zhao, Siting Yu, Hang Qi
المصدر: Gels, Vol 9, Iss 12, p 974 (2023)
بيانات النشر: MDPI AG, 2023.
سنة النشر: 2023
المجموعة: LCC:Science
LCC:Chemistry
LCC:Inorganic chemistry
LCC:General. Including alchemy
مصطلحات موضوعية: waste acrylic fiber, hydroplastization, micro-water method, alkaline hydrolysis, filtrate reducer, Science, Chemistry, QD1-999, Inorganic chemistry, QD146-197, General. Including alchemy, QD1-65
الوصف: Filtrate reducer is a drilling fluid additive that can effectively control the filtration loss of drilling fluid to ensure the safe and efficient exploitation of oilfields. It is the most widely used treatment agent in oilfields. Due to its moderate conditions and controllable procedure, alkaline hydrolysis of high-purity waste polyacrylonitrile has been utilized for decades to produce filtrate reducer on a large scale in oilfields. However, the issues of long hydrolysis time, high viscosity of semi-finished products, high drying cost, and tail gas pollution have constrained the development of the industry. In this study, low-purity waste acrylic fiber was first separated and purified using high-temperature hydroplastization, and the hydrolyzed product was obtained using alkaline hydrolysis with the micro-water method, which was called MW−HPAN. The hydrolysis reaction was characterized using X-ray diffraction, scanning electron microscopy, infrared spectroscopy, and thermogravimetric analysis, and the elemental analysis showed a hydrolysis degree of 73.21%. The experimental results showed that after aging at 180 °C for 16 h, the filtration volume of the freshwater base slurry with 0.30% dosage and 4% brine base slurry with 1.20% dosage was 12.7 mL and 18.5 mL, respectively. The microstructure and particle size analysis of the drilling fluid gel system showed that MW−HPAN could prevent the agglomeration of clay and maintain a reasonable particle size distribution even under the combined deteriorating effect of high temperature and inorganic cations, thus forming a dense filter cake and achieving a low filtrate volume of the drilling fluid gel system. Compared with similar commercially available products, MW−HPAN has better resistance to temperature and salt in drilling fluid gel systems, and the novel preparation method is promising to be extended to practical production.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 2310-2861
Relation: https://www.mdpi.com/2310-2861/9/12/974; https://doaj.org/toc/2310-2861
DOI: 10.3390/gels9120974
URL الوصول: https://doaj.org/article/7be5d6f1bb49442fab68d43da4501ef2
رقم الأكسشن: edsdoj.7be5d6f1bb49442fab68d43da4501ef2
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:23102861
DOI:10.3390/gels9120974