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Simplifying Nitration Chemistry with Bench-stable Organic Nitrating Reagents

التفاصيل البيبلوغرافية
العنوان: Simplifying Nitration Chemistry with Bench-stable Organic Nitrating Reagents
المؤلفون: Subrata Patra, Vasiliki Valsamidou, Dmitry Katayev
المصدر: CHIMIA, Vol 78, Iss 1/2 (2024)
بيانات النشر: Swiss Chemical Society, 2024.
سنة النشر: 2024
المجموعة: LCC:Chemistry
مصطلحات موضوعية: Nitration, Nitronium ion, Nitryl radicals, Organic nitrating reagent, Photoredox, Chemistry, QD1-999
الوصف: Nitro compounds play a crucial role in academia and industries, serving as building blocks for the synthesis of drugs, agrochemicals, and materials. Nitration, a fundamental process in organic synthesis, has undergone significant evolution since the 19th century. While electrophilic nitration dominates historically, recent decades have seen a focus on new reagents and their reactivity modes for achieving mild and robust synthesis of nitro compounds. Our group has a longstanding interest in developing cost-effective, readily available, recyclable nitrating reagents derived from organic scaffolds. These reagents serve as a controllable source of nitryl radical and nitronium ion species, enabling mild and practical nitration of hydrocarbons with exceptional functional group tolerance. This account details the development of nitrating reagents and their diverse applications in catalytic nitration across various classes of organic molecules.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: German
English
French
تدمد: 0009-4293
2673-2424
Relation: https://www.chimia.ch/chimia/article/view/7194; https://doaj.org/toc/0009-4293; https://doaj.org/toc/2673-2424
DOI: 10.2533/chimia.2024.32
URL الوصول: https://doaj.org/article/7d6157f362e14131912c7a08c074d1b4
رقم الأكسشن: edsdoj.7d6157f362e14131912c7a08c074d1b4
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:00094293
26732424
DOI:10.2533/chimia.2024.32