دورية أكاديمية
Visible-light-induced selective alkylsulfonylation of unactivated alkenes via remote heteroaryl migrations
| العنوان: | Visible-light-induced selective alkylsulfonylation of unactivated alkenes via remote heteroaryl migrations |
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| المؤلفون: | Xin Yuan, Jie Liu, Hao Lv, Long-Zhou Qin, Xiu Duan, Jian Wang, Meng-Yu Wu, Beining Chen, Jiang-Kai Qiu, Kai Guo |
| المصدر: | Green Synthesis and Catalysis, Vol 5, Iss 2, Pp 126-130 (2024) |
| بيانات النشر: | KeAi Communications Co. Ltd., 2024. |
| سنة النشر: | 2024 |
| المجموعة: | LCC:Chemical technology LCC:Biochemistry |
| مصطلحات موضوعية: | Visible-light-induced, Remote heteroaryl migrations, Alkylsulfonylation, Radical reaction, Unactivated alkenes, Chemical technology, TP1-1185, Biochemistry, QD415-436 |
| الوصف: | Photocatalyzed alkylsulfonylation of unactivated alkenes using DABCO. (SO2)2 and thianthrenium salts via a distal heteroaryl migration process has been developed, which provides a new means of synthesizing a variety of valuable alkylsulfonyl-substituted compounds. These alkylsulfonyl radicals couple with unactivated alkenes to undergo efficient intermolecular reactions, followed by distal heteroaryl migration. This mild catalytic method is tolerant of functional groups and affords medicinally relevant alkylsulfonylated heterocycles. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2666-5549 |
| Relation: | http://www.sciencedirect.com/science/article/pii/S2666554923000297; https://doaj.org/toc/2666-5549 |
| DOI: | 10.1016/j.gresc.2023.03.002 |
| URL الوصول: | https://doaj.org/article/7de69996765242439f583c9d7003ab5a |
| رقم الأكسشن: | edsdoj.7de69996765242439f583c9d7003ab5a |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 26665549 |
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| DOI: | 10.1016/j.gresc.2023.03.002 |