دورية أكاديمية
Preparation of N-B doped composite electrode for iron-chromium redox flow battery
العنوان: | Preparation of N-B doped composite electrode for iron-chromium redox flow battery |
---|---|
المؤلفون: | Yingchun Niu, Senwei Zeng, Guangfu Wu, Qingtan Gao, Ruichen Zhou, Chuanyuan Li, Yang Zhou, Quan Xu |
المصدر: | Green Energy and Intelligent Transportation, Vol 3, Iss 3, Pp 100158- (2024) |
بيانات النشر: | Elsevier, 2024. |
سنة النشر: | 2024 |
المجموعة: | LCC:Transportation engineering LCC:Renewable energy sources |
مصطلحات موضوعية: | Iron-chromium redox flow battery, N-B co-doped co-regulation, REDOX reaction rate, Performance, Transportation engineering, TA1001-1280, Renewable energy sources, TJ807-830 |
الوصف: | Iron-chromium redox flow battery (ICRFB) is an electrochemical energy storage technology that plays a vital role in dealing with the problems of discontinuity and instability of massive new energy generation and improving the acceptance capacity of the power grid. Carbon cloth electrode (CC) is the main site where the electrochemical reaction occurs, which always suffers from the disadvantages of poor electrochemical reactivity. A new N-B co-doped co-regulation Ti composite CC electrode (T-B-CC) is firstly generated and applied to ICRFB, where the REDOX reaction can be promoted significantly owing to the plentiful active sites generated on the modified electrode. As contrasted with ICRFB with normal CC electrode, after 50 battery charge/discharge cycles, the discharge capacity (1,990.3 mAh vs 1,155.8 mAh) and electrolyte utilization (61.88% vs 35.94%) of ICRFB with CC electrode (T-B-CC) are significantly improved. Furthermore, the energy efficiency (EE) is maintained at about 82.7% under 50 cycles, which is 9.3% higher than that of the pristine electrically assembled cells. The co-modulation of heteroatom doping and the introduction of Ti catalysts is a simple and easy method to improve the dynamics of the Cr3+/Cr2+ and Fe3+/Fe2+ reactions, enhancing the performance of ICRFBs. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 2773-1537 |
Relation: | http://www.sciencedirect.com/science/article/pii/S2773153724000100; https://doaj.org/toc/2773-1537 |
DOI: | 10.1016/j.geits.2024.100158 |
URL الوصول: | https://doaj.org/article/8202619db9034f81a046c1fdbee338d9 |
رقم الأكسشن: | edsdoj.8202619db9034f81a046c1fdbee338d9 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 27731537 |
---|---|
DOI: | 10.1016/j.geits.2024.100158 |