We analyze the contributions of the one–pion–pole (OPP) exchange, caused by strong low–energy interactions, and the pseudoscalar interaction beyond the Standard Model (BSM) to the correlation coefficients of the neutron β−–decays for polarized neutrons, polarized electrons and unpolarized protons. The strength of contributions of pseudoscalar interactions is defined by the effective coupling constant Cps=Cps(OPP)+Cps(BSM). We show that the contribution of the OPP exchange is of order Cps(OPP)∼−10−5. The effective coupling constant Cps(BSM) of the pseudoscalar interaction BSM can be in principle complex. Using the results, obtained by González-Alonso et al. (2019) [34] we find that the values of the real and imaginary parts of the effective coupling constant Cps(BSM) are constrained by −3.5×10−5