دورية أكاديمية
A core–shell copper oxides-cobalt oxides heterostructure nanowire arrays for nitrate reduction to ammonia with high yield rate
| العنوان: | A core–shell copper oxides-cobalt oxides heterostructure nanowire arrays for nitrate reduction to ammonia with high yield rate |
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| المؤلفون: | Hui Liu, Jingsha Li, Feng Du, Luyun Yang, Shunyuan Huang, Jingfeng Gao, Changming Li, Chunxian Guo |
| المصدر: | Green Energy & Environment, Vol 8, Iss 6, Pp 1619-1629 (2023) |
| بيانات النشر: | KeAi Communications Co., Ltd., 2023. |
| سنة النشر: | 2023 |
| المجموعة: | LCC:Renewable energy sources LCC:Ecology |
| مصطلحات موضوعية: | Electrocatalytic nitrate reduction, Ammonia production, Core–shell heterostructure, Copper oxides nanowire arrays, Cobalt oxides flocs, Renewable energy sources, TJ807-830, Ecology, QH540-549.5 |
| الوصف: | Electrochemical nitrate reduction to ammonia (NRA) can realize the green synthesis of ammonia (NH3) at ambient conditions, and also remove nitrate contamination in water. However, the current catalysts for NRA still face relatively low NH3 yield rate and poor stability. We present here a core–shell heterostructure comprising cobalt oxide anchored on copper oxide nanowire arrays (CuO NWAs@Co3O4) for efficient NRA. The CuO NWAs@Co3O4 demonstrates significantly enhanced NRA performance in alkaline media in comparison with plain CuO NWAs and Co3O4 flocs. Especially, at −0.23 V vs. RHE, NH3 yield rate of the CuO NWAs@Co3O4 reaches 1.915 mmol h−1 cm−2, much higher than those of CuO NWAs (1.472 mmol h−1 cm−2), Co3O4 flocs (1.222 mmol h−1 cm−2) and recent reported Cu-based catalysts. It is proposed that the synergetic effects of the heterostructure combing atom hydrogen adsorption and nitrate reduction lead to the enhanced NRA performance. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2468-0257 |
| Relation: | http://www.sciencedirect.com/science/article/pii/S2468025722000541; https://doaj.org/toc/2468-0257 |
| DOI: | 10.1016/j.gee.2022.03.003 |
| URL الوصول: | https://doaj.org/article/95d4b0fea39342089fb46e4cafca5395 |
| رقم الأكسشن: | edsdoj.95d4b0fea39342089fb46e4cafca5395 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 24680257 |
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| DOI: | 10.1016/j.gee.2022.03.003 |