Mechanical and tribological properties of nylon 6 and nylon 6/h-BN composites were investigated in this paper. Tensile, hardness, and impact tests were carried out for mechanical properties, while wear tests on pin-on-disc were carried out for tribological properties identification. Abrasion resistance tests were carried out on the TABER apparatus to analyze the abrasive wear of materials. SEM, XRD, and TGA were used to characterize the materials and to understand the distinctive features of nylon 6 and nylon 6/h-BN composites. Experimental results show that the mechanical properties and tribological behavior of nylon 6 got enhanced by the h-BN fillers. Tensile strength and modulus of elasticity were enhanced by 15.2% and 64.5%, respectively, while hardness and impact strength were enhanced by 3.45% and 6%, respectively. COF and wear rate of composites decreased up to 4 wt% filler reinforcement due to smooth transfer film formation. Coefficient of friction (COF) and wear resistance were improved by 10–15% and 8–10%, respectively, at various testing conditions. h-BN reinforcement in the matrix resulted in more weight loss due to abrasion and it reduced the abrasion resistance of nylon 6 by 5.5 times. Thermal stability was slightly increased, and crystallinity was little affected by the h-BN fillers.
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