دورية أكاديمية
Studying the mechanism and kinetics of fuel desulfurization using CexOy/NiOx piezo-catalysts as a new low-temperature method
| العنوان: | Studying the mechanism and kinetics of fuel desulfurization using CexOy/NiOx piezo-catalysts as a new low-temperature method |
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| المؤلفون: | Sangar S. Ahmed, Omid Amiri, Karwan M. Rahman, Savana J. Ismael, Noor S. Rasul, Darya Mohammad, Karukh A. Babakr, Nabaz A. Abdulrahman |
| المصدر: | Scientific Reports, Vol 13, Iss 1, Pp 1-16 (2023) |
| بيانات النشر: | Nature Portfolio, 2023. |
| سنة النشر: | 2023 |
| المجموعة: | LCC:Medicine LCC:Science |
| مصطلحات موضوعية: | Medicine, Science |
| الوصف: | Abstract In order to advance desulfurization technology, a new method for excellent oxidative desulfurization of fuel at room temperature will be of paramount importance. As a novel desulfurization method, we developed piezo-catalysts that do not require adding any oxidants and can be performed at room temperature. A microwave method was used to prepare CeO2/Ce2O3/NiOx nanocomposites. Model and real fuel desulfurization rates were examined as a function of synthesis parameters, such as microwave power and time, and operation conditions, such as pH and ultrasonic power. The results showed that CeO2/Ce2O3/NiOx nanocomposites demonstrated outstanding piezo-desulfurization at room temperature for both model and real fuels. Furthermore, CeO2/Ce2O3/NiOx nanocomposites exhibited remarkable reusability, maintaining 79% of their piezo-catalytic activity even after 17 repetitions for desulfurization of real fuel. An investigation of the mechanism of sulfur oxidation revealed that superoxide radicals and holes played a major role. Additionally, the kinetic study revealed that sulfur removal by piezo-catalyst follows a second-order reaction kinetic model. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2045-2322 |
| Relation: | https://doaj.org/toc/2045-2322 |
| DOI: | 10.1038/s41598-023-34329-y |
| URL الوصول: | https://doaj.org/article/c973e1b032e64100ad1343fff443741c |
| رقم الأكسشن: | edsdoj.973e1b032e64100ad1343fff443741c |
| قاعدة البيانات: | Directory of Open Access Journals |
Find this article in full text from Springer Verlag. 
Full Text Finder | تدمد: | 20452322 |
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| DOI: | 10.1038/s41598-023-34329-y |