In this work, an in-situ boride-reinforced Ti6Al4V compositionally graded material was prepared successfully by spark plasma sintering (SPS), and exhibited a good potential for military application because of its stepwise transition properties from a high-toughness end to a high-strength end along the thin-thickness direction. Microstructure characterization shows the chemical gradient ranged from 0 to 30 wt% TiB2 along the thickness direction, which was correlated with increasing micro-hardness values ranging from 565±5HV to 1270±5HV, respectively. The strength-toughness matching mechanisms of the gradient composites with different compositional gradients were discussed based on the static compression experiments and the dynamic Hopkinson compression rod experiments. The primary phases of the gradient composites included the α-Ti phase, β-Ti phase, remained TiB2 and in-situ formed whisker-like TiB phases. The composites with a compositional gradient of G84 (0, 0, 15, 30 wt%) exhibited the best impact resistance which achieved a good balance of high toughness and strength, and exhibited a compressive strength of 2148±5 MPa and a good elongation of 20 ± 0.5%. The strength-toughness matching mechanisms can be explained by the dispersion strengthening effect due to the presence of the in-situ formed TiB phase, and the consumption of more fracture energy by dislocation defects, which can prevent the crack propagation. Moreover, the pull-out of the whisker-like TiB phases toughened the gradient composites furthermore. This research demonstrated a reliable method for preparing TiB2/Ti–6Al-4Vgradient composites with high-impact resistance.
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