دورية أكاديمية
Synthesis and characterization of tough foldable and transparent poly(styrene-co-butyl acrylate)/nanoporous cellulose gel (NCG) nanocomposites
| العنوان: | Synthesis and characterization of tough foldable and transparent poly(styrene-co-butyl acrylate)/nanoporous cellulose gel (NCG) nanocomposites |
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| المؤلفون: | J. S. Borah, D. S. Kim |
| المصدر: | eXPRESS Polymer Letters, Vol 11, Iss 9, Pp 753-763 (2017) |
| بيانات النشر: | Budapest University of Technology, 2017. |
| سنة النشر: | 2017 |
| المجموعة: | LCC:Materials of engineering and construction. Mechanics of materials LCC:Chemical technology |
| مصطلحات موضوعية: | Polymer composites, Nanocomposites, Cellulose hydrogels, In-situ polymerization, Transparent flexible film, Materials of engineering and construction. Mechanics of materials, TA401-492, Chemical technology, TP1-1185 |
| الوصف: | Poly (styrene-co-butyl acrylate)/nanoporous cellulose gel nanocomposites [P (St/BA)/NCG] were synthesized by in-situ polymerization of styrene/butyl acrylate (St/BA) monomer mixtures in nanoporous regenerated cellulose gels. The three-dimensional nanoporous cellulose gels (NCGs) were fabricated via dissolution and coagulation of cellulose from aqueous sodium hydroxide (NaOH)/urea solution. The NCG contents in nanocomposites were controlled between 16 and 44% v/v by changing water content of starting hydrogels via compression dewatering. Scanning electron microscopy (SEM) analysis showed that the interconnected nanofibrillar network structure of NCGs was preserved well in the nanocomposites after insitu polymerization. The resulting nanocomposites exhibited excellent transparency (up to 82%) in the visible region and high mechanical strength, with a tensile strength of up to 56.0 MPa, Young’s modulus of up to 2195 MPa and elongation at break up to 80.9%. Dynamic mechanical analysis (DMA) showed a remarkable improvement (by over 3 orders of magnitude) in tensile storage modulus above glass transition temperature of the copolymer. The nanocomposites also showed significant improvements in thermal stability as well as water resistance over NCG. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1788-618X 18974546 |
| Relation: | http://www.expresspolymlett.com/letolt.php?file=EPL-0008120&mi=cd; https://doaj.org/toc/1788-618X |
| DOI: | 10.3144/expresspolymlett.2017.72 |
| URL الوصول: | https://doaj.org/article/9a8b23aa18974546b736231dd7546f08 |
| رقم الأكسشن: | edsdoj.9a8b23aa18974546b736231dd7546f08 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 1788618X 18974546 |
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| DOI: | 10.3144/expresspolymlett.2017.72 |