دورية أكاديمية
Di-μ-bromido-bis[benzyl(diethyl ether)magnesium]
العنوان: | Di-μ-bromido-bis[benzyl(diethyl ether)magnesium] |
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المؤلفون: | Mark A. Nesbit, Danielle L. Gray, Gregory S. Girolami |
المصدر: | Acta Crystallographica Section E, Vol 68, Iss 7, Pp m942-m942 (2012) |
بيانات النشر: | International Union of Crystallography, 2012. |
سنة النشر: | 2012 |
المجموعة: | LCC:Crystallography |
مصطلحات موضوعية: | Crystallography, QD901-999 |
الوصف: | The title benzyl Grignard reagent, [Mg2Br2(C7H7)2(C4H10O)2], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-molecule, the structural dimeric unit being generated by inversion symmetry with an Mg...Mg distance of 3.469 (2) Å. The Mg(II) atom exhibits a distorted tetrahedral coordination geometry. The crystal packing is defined by van der Waals interactions only. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 16005368 1600-5368 39815773 |
Relation: | http://scripts.iucr.org/cgi-bin/paper?S1600536812025445; https://doaj.org/toc/1600-5368 |
DOI: | 10.1107/S1600536812025445 |
URL الوصول: | https://doaj.org/article/9e8583ce7b7748ddb19de39815773ab5 |
رقم الأكسشن: | edsdoj.9e8583ce7b7748ddb19de39815773ab5 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 16005368 39815773 |
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DOI: | 10.1107/S1600536812025445 |