دورية أكاديمية
Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate
| العنوان: | Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate |
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| المؤلفون: | Yanpeng Xing, Miao Hu, Baoqing Liu, Jianhua Sun, Zhen Ma |
| المصدر: | Acta Crystallographica Section E, Vol 64, Iss 2, Pp m269-m269 (2008) |
| بيانات النشر: | International Union of Crystallography, 2008. |
| سنة النشر: | 2008 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | Crystallography, QD901-999 |
| الوصف: | The title complex, [Ag2(C7H7O3S)2(C25H22P2)2]·H2O, was obtained by the reaction of silver toluenesulfonate with diphenylphosphinomethane (dppm) in acetonitrile. There are two unique half-molecules of the complex in the asymmetric unit, together with one water molecule, which is disordered over two positions with site occupancy factors of 0.6 and 0.4. In each centrosymmetric neutral dimeric molecule, two Ag atoms are bridged by a pair of dppm ligands to give an eight-membered Ag2P4C2 ring with a distorted AgOP2 trigonal–planar environment. The Ag—Ag distances of 2.9215 (9) and 3.027 (1) Å indicate a direct bonding interaction. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 16005368 1600-5368 |
| Relation: | http://scripts.iucr.org/cgi-bin/paper?S1600536807067311; https://doaj.org/toc/1600-5368 |
| DOI: | 10.1107/S1600536807067311 |
| URL الوصول: | https://doaj.org/article/b2cf600e7e1845afa6656090f6ce8e56 |
| رقم الأكسشن: | edsdoj.b2cf600e7e1845afa6656090f6ce8e56 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 16005368 |
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| DOI: | 10.1107/S1600536807067311 |