دورية أكاديمية
Design and synthesis of charged porphyrin dimers for polyoxometalate recognition
العنوان: | Design and synthesis of charged porphyrin dimers for polyoxometalate recognition |
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المؤلفون: | Lamare, Raphaël, Ruppert, Romain, Elhabiri, Mourad, Ulrich, Gilles, Ruhlmann, Laurent, Weiss, Jean |
المصدر: | Comptes Rendus. Chimie, Vol 24, Iss S3, Pp 115-126 (2021) |
بيانات النشر: | Académie des sciences, 2021. |
سنة النشر: | 2021 |
المجموعة: | LCC:Biochemistry LCC:Physical and theoretical chemistry LCC:Mathematics |
مصطلحات موضوعية: | Porphyrins, Polyoxometalates, Molecular recognition, Fluorescence quenching, Host–guest chemistry, Biochemistry, QD415-436, Physical and theoretical chemistry, QD450-801, Mathematics, QA1-939 |
الوصف: | A series of porphyrin dimers have been prepared and characterized in order to form inclusion complexes with Lindqvist-type polyoxometallates. The synthesis of the porphyrin dimer has been optimized and can serve general purposes. The formation of inclusion complexes has been monitored using spectroscopic methods and moderate affinities with $\log \, K_{\mathrm{assoc}}$ varying from 2.6 to 4.2 have been determined and the parameters governing the formation of the complexes have been examined. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English French |
تدمد: | 1878-1543 |
Relation: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.105/; https://doaj.org/toc/1878-1543 |
DOI: | 10.5802/crchim.105 |
URL الوصول: | https://doaj.org/article/b536ba350fb3435281f8edc302075818 |
رقم الأكسشن: | edsdoj.b536ba350fb3435281f8edc302075818 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 18781543 |
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DOI: | 10.5802/crchim.105 |