دورية أكاديمية

Design and synthesis of charged porphyrin dimers for polyoxometalate recognition

التفاصيل البيبلوغرافية
العنوان: Design and synthesis of charged porphyrin dimers for polyoxometalate recognition
المؤلفون: Lamare, Raphaël, Ruppert, Romain, Elhabiri, Mourad, Ulrich, Gilles, Ruhlmann, Laurent, Weiss, Jean
المصدر: Comptes Rendus. Chimie, Vol 24, Iss S3, Pp 115-126 (2021)
بيانات النشر: Académie des sciences, 2021.
سنة النشر: 2021
المجموعة: LCC:Biochemistry
LCC:Physical and theoretical chemistry
LCC:Mathematics
مصطلحات موضوعية: Porphyrins, Polyoxometalates, Molecular recognition, Fluorescence quenching, Host–guest chemistry, Biochemistry, QD415-436, Physical and theoretical chemistry, QD450-801, Mathematics, QA1-939
الوصف: A series of porphyrin dimers have been prepared and characterized in order to form inclusion complexes with Lindqvist-type polyoxometallates. The synthesis of the porphyrin dimer has been optimized and can serve general purposes. The formation of inclusion complexes has been monitored using spectroscopic methods and moderate affinities with $\log \, K_{\mathrm{assoc}}$ varying from 2.6 to 4.2 have been determined and the parameters governing the formation of the complexes have been examined.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
French
تدمد: 1878-1543
Relation: https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.105/; https://doaj.org/toc/1878-1543
DOI: 10.5802/crchim.105
URL الوصول: https://doaj.org/article/b536ba350fb3435281f8edc302075818
رقم الأكسشن: edsdoj.b536ba350fb3435281f8edc302075818
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:18781543
DOI:10.5802/crchim.105