دورية أكاديمية

Significantly Enhanced Aqueous Cr(VI) Removal Performance of Bi/ZnO Nanocomposites via Synergistic Effect of Adsorption and SPR-Promoted Visible Light Photoreduction

التفاصيل البيبلوغرافية
العنوان: Significantly Enhanced Aqueous Cr(VI) Removal Performance of Bi/ZnO Nanocomposites via Synergistic Effect of Adsorption and SPR-Promoted Visible Light Photoreduction
المؤلفون: Xiaoya Yuan, Zijuan Feng, Jianjun Zhao, Jiawei Niu, Jiasen Liu, Dong Peng, Xin Cheng
المصدر: Catalysts, Vol 8, Iss 10, p 426 (2018)
بيانات النشر: MDPI AG, 2018.
سنة النشر: 2018
المجموعة: LCC:Chemical technology
LCC:Chemistry
مصطلحات موضوعية: surface plasmonic resonance, photoreduction, BiNPs/ZnO composite, hexavalent chromium, visible light, Chemical technology, TP1-1185, Chemistry, QD1-999
الوصف: Bismuth nanoparticles (BiNPs) and Zinc Oxide photocatalysts (BiNPs/ZnO) with different Bi loadings were successfully prepared via a facile chemical method. Their morphology and structure were thoroughly characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), UV-Vis (Ultraviolet-Visible) diffuse reflectance spectroscopy (DRS), photoluminescence spectra (PL), and electrochemical impedance spectroscopy (EIS). The results showed that a modification of hexagonal wurtzite-phase ZnO nanoparticles with Bi is achievable with an intimate interfacial interaction within its composites. The performance of the photocatalytic Cr(VI) removal under visible light irradiation indicated that BiNPs/ZnO exhibited a superior removal performance to bare ZnO, Bi, and the counterpart sample prepared using a physical mixing method. The excellent performance of the BiNPs/ZnO photocatalysts could be ascribed to the synergistic effect between the considerable physical Cr (VI) adsorption and enhanced absorption intensity in the visible light region, due to the surface plasmon resonance (SPR) as well as the effective transfer and separation of the photogenerated charge carriers at the interface.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 2073-4344
Relation: http://www.mdpi.com/2073-4344/8/10/426; https://doaj.org/toc/2073-4344
DOI: 10.3390/catal8100426
URL الوصول: https://doaj.org/article/acdb56d9f9584467a2181124cdd75273
رقم الأكسشن: edsdoj.b56d9f9584467a2181124cdd75273
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:20734344
DOI:10.3390/catal8100426