دورية أكاديمية

Phase Diagrams of the Quaternary System Na+, Mg2+, NH4+//SO42−-H2O at 288.15K and Their Application

التفاصيل البيبلوغرافية
العنوان: Phase Diagrams of the Quaternary System Na+, Mg2+, NH4+//SO42−-H2O at 288.15K and Their Application
المؤلفون: Xiangyi Zhang, Xuemin Gong, Jilin Cao, Qing Liu, Yajie LI
المصدر: Journal of Chemical Engineering of Japan, Vol 56, Iss 1 (2023)
بيانات النشر: Taylor & Francis Group, 2023.
سنة النشر: 2023
المجموعة: LCC:Chemical engineering
مصطلحات موضوعية: Astrakanite, Phase equilibrium, Salting-out method, Mg–N compound fertilizer, Na2SO4·10H2O, Chemical engineering, TP155-156
الوصف: In order to process and utilize the astrakanite resources comprehensively, the technology of (NH4)2SO4 salting-out method was proposed. On the base of the salt-water system phase equilibrium theory, The phase equilibrium solubilities of the quaternary system Na+, Mg2+, NH4+//SO42−-H2O and its subsystems at 288.15K were determined by isothermal method, and the phase diagrams were drawn. The results showed that the phase diagram of Na+, Mg2+, NH4+//SO42−-H2O system at 288.15K exists three co-saturation points and five crystallization fields, which the largest crystallization field is MgSO4·(NH4)2SO4·6H2O. The technique of processing astrakanite was proposed. The Mg–N compound fertilizer can be yielded with astrakanite and (NH4)2SO4 as the raw materials at 288.15K, and then Na2SO4·10H2O would be obtained when the remaining mother liquor was cooled to 273.15K. The method can separate and process astrakanite effectively with the advantages of simple operation, energy saving, environmental protection and so on, and can realize recycling production.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 00219592
1881-1299
0021-9592
Relation: https://doaj.org/toc/0021-9592; https://doaj.org/toc/1881-1299
DOI: 10.1080/00219592.2023.2197956
URL الوصول: https://doaj.org/article/b5cdbda65fed4c6cb0f515cba2c0337a
رقم الأكسشن: edsdoj.b5cdbda65fed4c6cb0f515cba2c0337a
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:00219592
18811299
DOI:10.1080/00219592.2023.2197956