دورية أكاديمية
Effect of Active Phase Precursor on Structural, Textural and Catalytic Properties of the Model NiOx/CeO2 System Active in Dry Reforming of Methane
| العنوان: | Effect of Active Phase Precursor on Structural, Textural and Catalytic Properties of the Model NiOx/CeO2 System Active in Dry Reforming of Methane |
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| المؤلفون: | Piotr Legutko, Marcin Kozieł, Andrzej Kowalczyk, Marek Michalik, Andrzej Adamski |
| المصدر: | Crystals, Vol 14, Iss 7, p 634 (2024) |
| بيانات النشر: | MDPI AG, 2024. |
| سنة النشر: | 2024 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | NiOx/CeO2, Ni precursor, structure and morphology, catalytic valorization of CO2, dry reforming of methane, Crystallography, QD901-999 |
| الوصف: | The current paper is devoted to the synthesis of ceria-supported nickel-based catalysts starting from different precursors of the nickel active phase. Thermal decomposition of metal-containing precursors, deposited onto stable supports by dry impregnation, belongs to the industrially preferred, simple ways of catalyst preparation. The synthesized series of NiOx/CeO2 catalysts have been tested in dry methane reforming (DMR), in which two greenhouse gases, i.e., CO2 and CH4, are simultaneously converted into syngas. Both reaction progress and stability of the catalyst strongly depend on nickel speciation, which in turn can be determined by the nature of the chosen precursor. Contrary to relatively many studies focused on the importance of synthetic methods and conditions on nickel speciation, the effect of precursor nature on structural, textural, and functional properties of catalytic systems has neither been discussed much nor fully understood. The main goal of this paper was to elucidate the effect of precursors on the properties of NiOx/CeO2. Consequences of the use of various nickel precursors (simple inorganic salts, organometallic complexes, and chelates) have been analyzed in detail from the viewpoint of their beneficial influence on the catalytic performance of NiOx/CeO2 system (containing 3 wt. % of Ni) tested in DMR. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 14070634 2073-4352 |
| Relation: | https://www.mdpi.com/2073-4352/14/7/634; https://doaj.org/toc/2073-4352 |
| DOI: | 10.3390/cryst14070634 |
| URL الوصول: | https://doaj.org/article/bac113c41655405fb9c26d7355381f6e |
| رقم الأكسشن: | edsdoj.bac113c41655405fb9c26d7355381f6e |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 14070634 20734352 |
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| DOI: | 10.3390/cryst14070634 |