دورية أكاديمية
Synthesis, characterization and CO2 adsorption studies of DABCO based pillared Zn-BDC and Co-BDC metal organic frameworks
| العنوان: | Synthesis, characterization and CO2 adsorption studies of DABCO based pillared Zn-BDC and Co-BDC metal organic frameworks |
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| المؤلفون: | Ijlal Aamer, Naseem Iqbal, Tayyaba Noor, Aisha Asghar |
| المصدر: | Materials Research Express, Vol 8, Iss 7, p 075506 (2021) |
| بيانات النشر: | IOP Publishing, 2021. |
| سنة النشر: | 2021 |
| المجموعة: | LCC:Materials of engineering and construction. Mechanics of materials LCC:Chemical technology |
| مصطلحات موضوعية: | BDC, synthesis, characterizations, CO2, DABCO, pillared, Materials of engineering and construction. Mechanics of materials, TA401-492, Chemical technology, TP1-1185 |
| الوصف: | This study focuses on pre-synthetic functionalized MOF material normally known as pillared layer MOFs. An additional component DABCO (1,4-diazabicyclo[2.2.2] octane) is added to the MOFs which works as a pillar to produce 3D structured MOFs. Zn-BDC-DABCO and Co-BDC-DABCO were studied for their performance in CO _2 capture application. The addition of DABCO turns the 2D-layered metal-BDC lattice into a 3D structure with enhanced performance for CO _2 capture. The MOFs were characterized using XRD, SEM, TGA, FTIR, and BET, and the CO _2 capture capacity was tested at 25 °C and 0–25 bar. Zn-BDC-DABCO and Co-BDC-DABCO showed a maximum adsorption capacity of 6.3 and 4.4 mmol g ^−1 CO _2 . |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2053-1591 |
| Relation: | https://doaj.org/toc/2053-1591 |
| DOI: | 10.1088/2053-1591/ac14ff |
| URL الوصول: | https://doaj.org/article/bf59410734b54046a91d73fc28dc80e6 |
| رقم الأكسشن: | edsdoj.bf59410734b54046a91d73fc28dc80e6 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 20531591 |
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| DOI: | 10.1088/2053-1591/ac14ff |