دورية أكاديمية
Determination of the Ionization Constants of Some Benzoyl Thiourea Derivatives in Dioxane-Water Mixture
| العنوان: | Determination of the Ionization Constants of Some Benzoyl Thiourea Derivatives in Dioxane-Water Mixture |
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| المؤلفون: | Gun Binzet, Bülent Zeybek, Esma Kılıç, Nevzat Külcü, Hakan Arslan |
| المصدر: | Journal of Chemistry, Vol 2013 (2013) |
| بيانات النشر: | Wiley, 2013. |
| سنة النشر: | 2013 |
| المجموعة: | LCC:Chemistry |
| مصطلحات موضوعية: | Chemistry, QD1-999 |
| الوصف: | The stoichiometric ionization constants of N,N-dialkyl-N′-(4-substituted benzoyl) thiourea (Substitutes: H, Cl, and Br; alkyl groups: ethyl, n-propyl, n-butyl, and phenyl) derivatives have been determined potentiometrically in dioxane-water (v:v, 50:50) mixture at ionic strength of 0.1 M and 25.0±0.1°C. The ionization constants were calculated with the BEST computer program and the formation curves using the data obtained from the potentiometric titrations. The effects of substituents and alkyl groups on the ionization constants of the benzoyl thiourea derivatives have been investigated. A comparison of the basicities of ethyl, n-propyl, and n-butyl thiourea derivatives (−C2H5 |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2090-9063 2090-9071 |
| Relation: | https://doaj.org/toc/2090-9063; https://doaj.org/toc/2090-9071 |
| DOI: | 10.1155/2013/201238 |
| URL الوصول: | https://doaj.org/article/ef178ba848b94ac1bc31c3a330a90d0f |
| رقم الأكسشن: | edsdoj.f178ba848b94ac1bc31c3a330a90d0f |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 20909063 20909071 |
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| DOI: | 10.1155/2013/201238 |