دورية أكاديمية
Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) Block Copolymer by Redox Polymerization and Atom Transfer Radical Polymerization
| العنوان: | Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) Block Copolymer by Redox Polymerization and Atom Transfer Radical Polymerization |
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| المؤلفون: | Melahat Göktaş, Guodong Deng |
| المصدر: | Indonesian Journal of Chemistry, Vol 18, Iss 3, Pp 537-543 (2018) |
| بيانات النشر: | Department of Chemistry, Universitas Gadjah Mada, 2018. |
| سنة النشر: | 2018 |
| المجموعة: | LCC:Chemistry |
| مصطلحات موضوعية: | atom transfer radical polymerization, redox polymerization, macroinitiator, block copolymer, methyl methacrylate, Chemistry, QD1-999 |
| الوصف: | Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) [PMMA-b-PNIPAM] block copolymers were obtained by a combination of redox polymerization and atom transfer radical polymerization (ATRP) methods in two steps. For this purpose, PMMA macroinitator (ATRP-macroinitiator) was synthesized by redox polymerization of methyl methacrylate and 3-bromo-1-propanol using Ce(NH4)2(NO3)6 as a catalyst. The synthesis of PMMA-b-PNIPAM block copolymers was carried out by means of ATRP of ATRP-macroinitiator and NIPAM at 60 °C. The block copolymers were obtained in high yield and high molecular weight. The characterization of products was accomplished by using multi instruments and methods such as nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, gel permeation chromatography, and thermogravimetric analysis. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1411-9420 2460-1578 |
| Relation: | https://jurnal.ugm.ac.id/ijc/article/view/28645; https://doaj.org/toc/1411-9420; https://doaj.org/toc/2460-1578 |
| DOI: | 10.22146/ijc.28645 |
| URL الوصول: | https://doaj.org/article/ef423919ddd44bf18c94913159bf2de1 |
| رقم الأكسشن: | edsdoj.f423919ddd44bf18c94913159bf2de1 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 14119420 24601578 |
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| DOI: | 10.22146/ijc.28645 |