دورية أكاديمية
Spin-Crossover and Slow Magnetic Relaxation Behavior in Hexachlororhenate(IV) Salts of Mn(III) Complexes [Mn(5-Hal-sal2323)]2[ReCl6] (Hal = Cl, Br)
| العنوان: | Spin-Crossover and Slow Magnetic Relaxation Behavior in Hexachlororhenate(IV) Salts of Mn(III) Complexes [Mn(5-Hal-sal2323)]2[ReCl6] (Hal = Cl, Br) |
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| المؤلفون: | Aleksandra V. Tiunova, Anna V. Kazakova, Denis V. Korchagin, Gennady V. Shilov, Sergey M. Aldoshin, Aleksei I. Dmitriev, Mikhail V. Zhidkov, Konstantin V. Zakharov, Eduard B. Yagubskii |
| المصدر: | International Journal of Molecular Sciences, Vol 23, Iss 19, p 11449 (2022) |
| بيانات النشر: | MDPI AG, 2022. |
| سنة النشر: | 2022 |
| المجموعة: | LCC:Biology (General) LCC:Chemistry |
| مصطلحات موضوعية: | spin-crossover, MnIII(sal2323) complexes, hexahalorhenates, polyfunctional compounds, magnetic properties, single-ion magnet, Biology (General), QH301-705.5, Chemistry, QD1-999 |
| الوصف: | The cationic complexes of Mn(III) with the 5-Hal-sal2323 (Hal = Cl, Br) ligands and a paramagnetic doubly charged counterion [ReCl6]2− have been synthesized: [Mn(5-Cl-sal2323)]2[ReCl6] (1) and [Mn(5-Br-sal2323)]2[ReCl6] (2). Their crystal structures and magnetic properties have been studied. These isostructural two-component ionic compounds show a thermally induced spin transition at high temperature associated with the cationic subsystem and a field-induced slow magnetic relaxation of magnetization at cryogenic temperature, associated with the anionic subsystem. The compounds are the first examples of the coexistence of spin crossover and field-induced slow magnetic relaxation in the family of known [MnIII(sal2323)] cationic complexes with various counterions. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1422-0067 1661-6596 |
| Relation: | https://www.mdpi.com/1422-0067/23/19/11449; https://doaj.org/toc/1661-6596; https://doaj.org/toc/1422-0067 |
| DOI: | 10.3390/ijms231911449 |
| URL الوصول: | https://doaj.org/article/f9a8d9c2929347ee90b45bc518cb8d13 |
| رقم الأكسشن: | edsdoj.f9a8d9c2929347ee90b45bc518cb8d13 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 14220067 16616596 |
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| DOI: | 10.3390/ijms231911449 |