دورية أكاديمية
[1,2-Bis(diphenylphosphanyl)ethane-κ2P,P′]{2-[(4-nitrobenzoylmethyl)diphenylphosphanyl]phenyl-κ2C,C′}palladium(II) trifluoromethanesulfonate–dichloromethane–n-hexane (1/1/0.5)
| العنوان: | [1,2-Bis(diphenylphosphanyl)ethane-κ2P,P′]{2-[(4-nitrobenzoylmethyl)diphenylphosphanyl]phenyl-κ2C,C′}palladium(II) trifluoromethanesulfonate–dichloromethane–n-hexane (1/1/0.5) |
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| المؤلفون: | Corrado Rizzoli, Kazem Karami, Farzaneh Borzooie |
| المصدر: | Acta Crystallographica Section E, Vol 67, Iss 4, Pp m416-m417 (2011) |
| بيانات النشر: | International Union of Crystallography, 2011. |
| سنة النشر: | 2011 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | Crystallography, QD901-999 |
| الوصف: | In the cation of the title compound, [Pd(C26H19NO3P)(C26H24P2)]CF3O3S·CH2Cl2·0.5C6H14, the PdII atom has a slightly tetrahedrally distorted square-planar coordination geometry. The PdC3P and PdC2P2 five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, intermolecular C—H...O hydrogen bonds link cations and anions into a three-dimensional network. The dichloromethane solvent molecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent molecule has a crystallographically imposed centre of symmetry. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 16005368 1600-5368 |
| Relation: | http://scripts.iucr.org/cgi-bin/paper?S1600536811008075; https://doaj.org/toc/1600-5368 |
| DOI: | 10.1107/S1600536811008075 |
| URL الوصول: | https://doaj.org/article/fc1741c782c842d1b66414c7253cba45 |
| رقم الأكسشن: | edsdoj.fc1741c782c842d1b66414c7253cba45 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 16005368 |
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| DOI: | 10.1107/S1600536811008075 |