دورية أكاديمية
Organocatalytic and enantioselective Michael reaction between α-nitroesters and nitroalkenes. Syn/anti-selectivity control using catalysts with the same absolute backbone chirality
| العنوان: | Organocatalytic and enantioselective Michael reaction between α-nitroesters and nitroalkenes. Syn/anti-selectivity control using catalysts with the same absolute backbone chirality |
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| المؤلفون: | Jose I. Martínez, Uxue Uria, Maria Muñiz, Efraím Reyes, Luisa Carrillo, Jose L. Vicario |
| المصدر: | Beilstein Journal of Organic Chemistry, Vol 11, Iss 1, Pp 2577-2583 (2015) |
| بيانات النشر: | Beilstein-Institut, 2015. |
| سنة النشر: | 2015 |
| المجموعة: | LCC:Science LCC:Organic chemistry |
| مصطلحات موضوعية: | asymmetric diastereodivergent, enantioselective, Michael addition, nitroalkenes, nitroesters, organocatalysis, squaramides, Science, Organic chemistry, QD241-441 |
| الوصف: | The asymmetric and catalytic Michael reaction between α-nitroesters and nitroalkenes has been studied in the presence of two bifunctional catalysts both containing the same absolute chirality at the carbon backbone. The reaction performed in similar conditions allows us to control the syn or anti selectivity of the Michael adduct obtaining good yields and high enantiocontrol in all cases. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1860-5397 |
| Relation: | https://doaj.org/toc/1860-5397 |
| DOI: | 10.3762/bjoc.11.277 |
| URL الوصول: | https://doaj.org/article/fd9be3fbe978495d93839551d964679f |
| رقم الأكسشن: | edsdoj.fd9be3fbe978495d93839551d964679f |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 18605397 |
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| DOI: | 10.3762/bjoc.11.277 |