مورد إلكتروني
Remarkable Acceleration of Benzimidazole Synthesis and Cyanosilylation Reactions in a Supramolecular Solid Catalyst
| العنوان: | Remarkable Acceleration of Benzimidazole Synthesis and Cyanosilylation Reactions in a Supramolecular Solid Catalyst |
|---|---|
| بيانات النشر: | John Wiley & Sons Hispana 2017 |
| تفاصيل مُضافة: | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química Universitat Politècnica de València. Departamento de Química - Departament de Química Ministerio de Economía y Competitividad Generalitat Valenciana Rojas-Buzo, Sergio García-García, Pilar Corma Canós, Avelino |
| نوع الوثيقة: | Electronic Resource |
| مستخلص: | [EN] A solid metal organic catalyst with hydrophobic pockets and Lewis acid centers strongly accelerates the reaction rate for organic reactions. This is exemplified for the cyanosilylation of ketones and for the synthesis of benzimidazoles, for which very high selectivities are obtained. The solid can be recovered and reused and its behavior approaches that of a functional enzyme mimic. |
| مصطلحات الفهرس: | Benzimidazole, Cyanosilylation, Enzyme mimic, Metal organic catalyst, Supramolecular catalyst, QUIMICA ORGANICA, info:eu-repo/semantics/article |
| URL: | |
| الإتاحة: | Open access content. Open access content http://rightsstatements.org/vocab/InC/1.0 info:eu-repo/semantics/openAccess |
| ملاحظة: | TEXT English |
| أرقام أخرى: | UPV oai:riunet.upv.es:10251/105365 urn:issn:1867-3880 info:doi:10.1002/cctc.201601407 1044755708 |
| المصدر المساهم: | UNIVERSITAT POLITECNICA DE VALENCIA From OAIster®, provided by the OCLC Cooperative. |
| رقم الأكسشن: | edsoai.on1044755708 |
| قاعدة البيانات: | OAIster |
| الوصف غير متاح. |