مورد إلكتروني
Solvatochromism of 5-(4-substituted arylazo)-4-phenyl-6-methyl-3-cyano-2-pyridones
| العنوان: | Solvatochromism of 5-(4-substituted arylazo)-4-phenyl-6-methyl-3-cyano-2-pyridones |
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| عناروين إضافية: | Solvatohromizam 5-(4-supstituisanih arilazo)-4-fenil-6-metil-3-cijano-2-piridona |
| المصدر: | Zaštita materijala |
| بيانات النشر: | Engineering Society for Corrosion, Belgrade, Serbia 2018 |
| تفاصيل مُضافة: | Valentić, Nataša Lađarević, Jelena Božić, Bojan Mijin, Dušan Ušćumlić, Gordana |
| نوع الوثيقة: | Electronic Resource |
| مستخلص: | Eight 5-(4-substituted arylazo)-4-phenyl-6-methyl-3-cyano-2-pyridones were synthesized by reaction of benzoylacetone and arendiazonium salt, followed by condensation with cyanoacetamide. Absorption spectra of all azo pyridone dyes were recorded in twelve protic and aprotic solvents in the range of 200-600 nm. A simple Hammett equation was used to study the effect of the substituents on the absorption spectra of these azo dyes. The solute-solvent interactions were clarified on the basis of linear solvation energy relationships concept proposed by Kamlet and Taft. The results showed that the solvent effects on the absorption spectra of the investigated azo dyes were very complex and strongly dependent on the nature of the substituents on the phenylazo group. Osam 5-(4-supstituisanih arilazo)-4-fenil-6-metil-3-cijano-2-piridona je sintetizovano reakcijom benzoilacetona i arendiazonijumove soli, i kondenzacijom nastalog proizvoda sa cijano-acetamidom. Apsorpcioni spektri dobijenih arilazo piridonskih boja su snimljeni u dvanaest protičnih i aprotičnih rastvarača u opsegu od 200-600 nm. Za proučavanje uticaja supstituenata na apsorpcione spektre ispitivanih azo boja korišćena je prosta ametova jednačina. Interakcije rastvorak-rastvarač su razjašnjene na osnovu koncepta linearne korelacije energije solvatacije, koji su predložili Kamlet i Taft. Rezultati pokazuju da su efekti rastvarača na apsorpcione spektre istraženih azo boja veoma kompleksni i jako zavise od prirode supstituenata na fenilazo grupi. |
| مصطلحات الفهرس: | Arylazo pyridone dyes, solvent effects, substituent effects, absorption spectra, arilazo piridonske boje, uticaj rastvarača, uticaj supstituenata, apsorpcioni spektri, article |
| URL: | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS |
| الإتاحة: | Open access content. Open access content https://creativecommons.org/licenses/by-nc-nd/4.0 BY-NC-ND openAccess |
| ملاحظة: | Zaštita materijala |
| أرقام أخرى: | RSPST oai:TechnoRep.tmf.bg.ac.rs:123456789/3834 0351-9465 10.5937/ZasMat1801119V conv_412 1242560233 |
| المصدر المساهم: | UIVERSITY OF BELGRADE From OAIster®, provided by the OCLC Cooperative. |
| رقم الأكسشن: | edsoai.on1242560233 |
| قاعدة البيانات: | OAIster |
| الوصف غير متاح. |