Regiospecific N-Arylation of Aliphatic Amines under Mild and Metal-Free Reaction Conditions
| العنوان: | Regiospecific N-Arylation of Aliphatic Amines under Mild and Metal-Free Reaction Conditions |
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| المؤلفون: | Purkait, Nibadita, Kervefors, Gabriella, Linde, Erika, Olofsson, Berit |
| المصدر: | Angewandte Chemie International Edition. 57(35):11427-11431 |
| مصطلحات موضوعية: | anilines, arylamines, diaryliodonium salts, hypervalent iodine, metal-free reactions |
| الوصف: | A transition metal-free N-arylation of primary and secondary amines with diaryliodonium salts is presented. Both acyclic and cyclic amines are well tolerated, providing a large set of N-alkyl anilines. The methodology is unprecedented among metal-free methods in terms of amine scope, the ability to transfer both electron-withdrawing and electron-donating aryl groups, and efficient use of resources, as excess substrate or reagents are not required. |
| وصف الملف: | electronic |
| URL الوصول: | https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-160074 https://doi.org/10.1002/anie.201807001 https://su.diva-portal.org/smash/get/diva2:1251849/FULLTEXT01.pdf |
| قاعدة البيانات: | SwePub |
| تدمد: | 14337851 15213773 |
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| DOI: | 10.1002/anie.201807001 |